Synthesis of Tungsten Oxo Alkylidene Complexes
نویسندگان
چکیده
منابع مشابه
Z-Selective olefin metathesis reactions promoted by tungsten oxo alkylidene complexes.
Addition of LiOHMT (OHMT = O-2,6-dimesitylphenoxide) to W(O)(CH-t-Bu)(PMe(2)Ph)(2)Cl(2) led to WO(CH-t-Bu)Cl(OHMT)(PMe(2)Ph) (4). Subsequent addition of Li(2,5-Me(2)C(4)H(2)N) to 4 yielded yellow W(O)(CH-t-Bu)(OHMT)(Me(2)Pyr)(PMe(2)Ph) (5). Compound 5 is a highly effective catalyst for the Z-selective coupling of selected terminal olefins (at 0.2% loading) to give product in >75% yield with >99...
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A variety of molybdenum or tungsten complexes that contain a tert-butylimido ligand have been prepared. For example, the o-methoxybenzylidene complex W(N-t-Bu)(CH-o-MeOC6H4)(Cl)2(py) was prepared through addition of pyridinium chloride to W(N-t-Bu)2(CH2-o-MeOC6H4)2, while Mo(N-t-Bu)(CH-o-MeOC6H4)(ORF)2(tBuNH2) complexes (ORF = OC6F5 or OC(CF3)3) were prepared through addition of two equivalents...
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ژورنال
عنوان ژورنال: Organometallics
سال: 2012
ISSN: 0276-7333,1520-6041
DOI: 10.1021/om3008579